| Place | Rider's name | Team's name | Time |
|---|---|---|---|
| 1 | Mikel Nieve | EUSKADI (EUSKALTEL-EUSKADI) | 4:51:59 |
| 2 | Frank Schleck | Saxo Bank | |
| 3 | Weert Kevin De | QUICK-STEP | |
| 4 | Joaquim Rodríguez | Katusha | 0:01:22 |
| 5 | Luis Leon Sanchez | Caisse D'Epargne | 0:01:32 |
| 6 | Muñoz Ezequiel Mosquera | Xacobeo-Galicia | 0:01:40 |
| 7 | Dapena David Garcia | Xacobeo-Galicia | 0:01:42 |
| 8 | Nicolas Roche | AG2R PREVOYANCE-DECATHLON | 0:01:44 |
| 9 | Carlos Sastre | Cervelo | 0:01:50 |
| 10 | Vincenzo Nibali | LIQUIGAS | 0:01:56 |